FlexisignPro10Keygen


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FlexisignPro10Keygen

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See also
jSign

References

External links
Flexiscan web site
Flexisign Pro Licensing Info

Category:PDF software
Category:Web servicesThis invention relates to a process for the preparation of trifluoromethanesulfonyloxy-containing compounds. More specifically, this invention relates to a process for the preparation of trifluoromethanesulfonyloxy-containing compounds from haloalkanethiols. The processes of this invention may be used to prepare, for example, (trifluoromethanesulfonyloxy)acetaldehyde, trifluoromethanesulfonyloxyacetic acid, (trifluoromethanesulfonyloxy)acetyl esters, and trifluoromethanesulfonyloxyacetonitrile. Trifluoromethanesulfonyloxy acetic acid may be used, for example, as a Friedel-Crafts acceptor in Friedel-Crafts reactions.
The preparation of trifluoromethanesulfonyloxy-containing compounds by the reaction of acetonitrile or nitromethane with sulfuryl fluoride in the presence of a palladium catalyst has been reported. See, for example, G. I. Michelson et al., Tetrahedron Letters 7, 1065 (1965) and R. N. Hannabarger et al., Journal of Organic Chemistry 30, 4218 (1965). Both of these references teach that the product of these reactions is a mixture of at least three isomers which can be separated by fractional distillation to provide the trifluoromethanesulfonyloxy-containing compounds in very low yields.
The reactions of haloalkanethiols with chlorosulfonyl or bromosulfonyl fluorides to produce aryl or alkyl sulfonyl fluorides are known. See, for example, K. Langer et al., Annals of the New York Academy of Sciences, Vol. 118, pp. 173, (1968) and U.S. Pat. No. 4,107,017. However, these reactions give products which are not the desired trifluoromethanesulfonyloxy-containing compounds.
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